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外文翻译中文译文和致谢

外文翻译中文译文和致谢
外文翻译中文译文和致谢

外文翻译

Coagulation and flocculation

14.1

Introduction

Coagulation and flocculation provide the water treat-ment process by which finely divided suspended and colloidal matter in the water is made to agglomerate and form flocs. This enables their removal by sedi-mentation, dissolved air flotation or filtration. Colloidal particles (colloids) are midway in size 1 between dissolved solids and suspended matter. Colloids are kept in suspension (stabilised) by electrostatic repulsion and hydration.Electrostatic repulsion occurs because colloids usually have a surface charge due to the presence of a double layer of ions around each particle. Thus, the colloid has an electric charge, mostly a negative one. Hydration is the reaction of particles at their surface with the surrounding water. The resulting particle-water agglomerates have a specific gravity, which differs little from that of water itself.

The substances that frequently are to be removed by coagulation and flocculation are those that cause turbidity and colour. Surface waters in tropical countries often are turbid and contain colouring material. Turbidity may result from soil erosion, algal growth or animal/vegetable debris carried by surface run-off. Substances leached from decomposed organic matter, leaves, or soil such as peat may impart colour. Both turbidity and colour are mostly present as colloidal particles.

The electrostatic repulsion between colloidal particles effectively cancels out the electronic attraction forces (Van der Waals?ˉforces) that would attach the particles together. Certain chemicals (called coagulating agents, coagulants) have the capacity to compress the double layer of ions around the colloidal particles. They reduce the range of the electrostatic repulsion, and thus enable the particles to flocculate, i.e. to form flocs. These flocs can grow to a sufficient size and specific weight to allow their removal by settling, flotation or filtration.

Generally water treatment processes involving the use of chemicals are not so suitable for small community water supplies. They should be avoided whenever possible. Chemical coagulation and flocculation should only be used when the needed treatment result cannot be achieved with another treatment process using no chemicals. If the turbidity and colour of the raw water are not much higher than is permissible for drinking water, it should be possible to avoid chemical coagulation in the treatment of the water. A process such as slows and filtration or multi-stage filtration would serve both to reduce the turbidity and colour to acceptable levels, and to improve the other water quality characteristics, in a single unit.A roughing filter can serve to reduce the turbidity load on the slow sand filter, if necessary.

.

14.2Coagulants

Alum (Al2(SO4)3.nH20) where n=14, 16, or 18, depends on the form of alum supplied. This may be in liquid solution, broken crystalline granules 2-5 cm size (kibbled) or crystalline blocks. It is by far the most widely used coagulant. Iron salts (e.g. ferric chloride (FeCl3), orferric sulphate (Fe2(SO4)3.9H2O) can be used as well

and in some instances have advantages over alum. A significant advantage of iron salts over aluminium is the broader pH2 range for good coagulation. Thus, in the treatment of soft coloured waters where colour removal is best obtained at low pHs, iron salts may be preferred as coagulants. Iron

salts should also be considered for coagulation at high pHs, since ferric hydroxide is highly insoluble in contrast to aluminium salts, which form soluble aluminate ions at high pHs. Sodium aluminate is mostly used for coagulation at medium pHs. Synthetic organic polyelectrolytes have become available as coagulants but are generally not economical for small water supply systems, nor are they readily available.

The use of extracts from the crushed seeds of certain tropical trees is described in detail in the next section, 14.3.

Coagulants such as soluble aluminium and iron salts react with the alkalinity of the water, and hydrolyse in it. For example, alum reacts to form aluminium-hydroxide floc,Al(OH)3, a gelatinous precipitate. The required alkalinity may be naturally present in the water or it has to be added through dosage of lime, Ca(0H)2or sodium carbonate,Na2CO3(also called soda ash).

For good coagulation the optimal dose of coagulant should be fed into the water and quickly and properly mixed with it. The optimal dose will vary depending upon the nature of the raw water and its overall composition. It is not possible to compute the optimal coagulant dose for a particular raw water. A laboratory experiment called the jar test is generally used for the periodic determination of the optimal dose.

The jar test may be briefly described as follows:A series of samples of water are placed on a special multiple stirrer and the samples,typically 800 ml in 1-litre beakers (or jars), are dosed with a range of coagulant, e.g. 10,20, 30, 40 and 50 mg/l, and are stirred vigorously for about one minute. Then follows a gentle stirring (10 minutes), after which the samples are allowed to stand and settle for 30-60 minutes. The samples are then examined for colour and turbidity and the lowest dose of coagulant that gives satisfactory clarification of the water is noted.

A second test involves the preparation of samples with the pH adjusted so that the samples cover a range (e.g. pH = 5, 6, 7 and 8). The coagulant dose determined previously is added to each beaker. Then follows stirring, flocculation and settlement as before. After this, the samples are examined and the optimum pH is determined. If necessary, a re-check of the minimum coagulant dose can be done.

As mentioned earlier, aluminium and iron salts have considerable differences in their pH zones of good coagulation. For alum the pH zone for optimum coagulation is quite narrow, ranging from about 6.5-7.5. The comparable range for ferric sulphate is considerably broader, a pH range of about 5.5-9.0 (Fig. 14.1). When the results of a jar test are plotted, this type of curve is typical.

The most common method of dosing the alum or ferric sulphate is in the form of a solution. Such a solution (usually of 3-7% strength, that is, 30-70 kg alum Al2(SO4)3.14H2O per m3 water) is prepared in special tanks with a holding capacity of ten or more hours coagulant feeding requirements. Two tanks are required, one in operation, while the solution is being prepared in the other.

When using alum, one should keep in mind that in solutions of less than 1%

strength,the chemical is hydrolysed (i.e. forms agglomerates with the chemical feed water) before it is dosed into the raw water. To prevent this, the solution should always have a strength of more than 1.5%.

Various chemical feed arrangements can be used. Figure 14.2 shows an example.

The simplest method of using lime is in the form of a suspension led into a special tank(called a lime saturator), to produce a saturated solution of calcium hydroxide. The size of the tank depends on the required lime dosage.

14.3Coagulation and flocculation with extracts of particular seeds.

Special contribution from Dr. Samia Al Azharia Jahn, Water Treatment Adviser. Botanical identification

Early attempts at water coagulation with pla nt materials arose through “self-help” by poor people who had no access to groundwater. In India the seeds of Strychnos potatorum (table 14.1) have been used to clarify turbid water since the first centuries AD. Where this wild tree was not available, kernels of Prunus species and seeds of legumes (Papilionoidea) became substitutes. In the Northern Sudan, seeds of Moringaoleifera were tried out instead of beans and groundnuts. A relationship between the botanical type and a content of coagulants (chemotaxonomy) could be detected for several plant genera and families.

Chemical composition and toxicology

Certain seeds contain substances for the growth of the seedling, which also have flocculating properties. The polyelectrolytes of Moringa oleifera, M. stenopetala and Strychnos potatorum are examples of such flocculating substances (table 14.1). The destabilisation of water colloids is due to positive or negative charges. The cationic electrolytes of Moringa are presumed to act like cations of metal coagulants. Alum and a seed extract different impacts on several chemical and physical characteristics of coagulation (table 14.2). Moringa seeds contain seed oil and a germicide. The smell and taste effect on the water is very small, even for the maximum Moringa seed dose (200-250mg/l). In the low range of the optimal doses there is no germicide effect and there are no risks from toxic substances. The possible health effects from toxic substances in Strychnos potatorum seeds and Prunus kernels have not been investigated yet (Jahn, 1988, 1994).

Seed quality

Only ripe Moringa oleifera seeds (with brown seed coat) give a high coagulant efficiency(Jahn, 1986). Improper treatment of the seeds leads to loss of coagulation capacity. It can be prevented if collection and treatment is done by agro-foresters or trained women and by using correct equipment.

Turbidity range

Experiences with seed coagulation relate to highly turbid waters only. If

optimal doses and proper stirring are applied, seed extracts of Moringa oleifera can also reduce low turbidity levels to 5-10 NTU after one hour of settling. For raw water with turbidity below 30 NTU, alum is superior in performance (table 14.2). Thus, surface waters with varying turbidity (below 30 NTU for certain periods of the year) cannot always be treated adequately with seed extracts alone but need coagulant aids during such low turbidity periods. Use of coagulant aids is not feasible at household

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铝、钙对熔融铁的复合脱氧平衡 天鸷田口,秀ONO-NAKAZATO,Tateo USUI,Katsukiyo MARUKAWA,肯KATOGI和Hiroaki KOSAKA。 研究生和JSPS研究员, 工程研究院,大阪大学,2-1山田丘, 吹田,大阪565 - 0871日本。 1)材料科学与工程课程,材料科学和制造分支,工程研究院,大阪大学, 2-1山田丘, 吹田, 大阪565 - 0871日本。 2)高端科技创新中心、大阪大学,2-1山田丘,吹田,大阪565 - 0871日本。 3)Electro-Nite贺利日本,有限公司,1-7-40三岛江,高槻,大阪569 - 0835日本。 4)TOYO工程研究中心有限公司,2-2-1春日,茨城,大阪567 - 0031日本。 (发表2005年6月17日,刊发于2005年7月20日) 氧夹杂对钢液的炼钢反应的影响是很显著的,例如脱硫。控制钢液氧含量是很重要的。使用良好的脱氧剂(如铝、钙),有效减少钢液的氧含量。研究者已经在复合脱氧方面做了一些探究。然而,实验数据不完全符合热力学数据计算值。因为没有具体可以利用的熔融铁钙脱氧的确切热力学数据。在本研究中,铝、钙对熔融铁的复合脱氧平衡控制在1873K。Al-Ca在熔铁脱氧中氧活度通过测量电动势(EMF)的方法求得。Al-Ca复合脱氧平衡实验的有效性由过去的和现在的研究结果共同综合判断的,本实验的Al-Ca脱氧平衡能够比过去的研究更好地反应Fe-Al-Ca-O系的关系。 关键词:复合脱氧,铝合金,钙,氧活度,电动势方法,炼钢,生石灰,氧化铝。 1前言 近年来,随着对超洁净钢的要求越来越高,需要更严格地控制钢中夹杂物。降低和控制钢中夹杂物含量在几个ppm以内。特别地,氧夹杂在钢液炼钢反应中的影响(例如脱硫)是非常大的,控制钢液中氧含量是非常重要的。使用强脱氧剂(如铝、钙)有效降低钢液的氧含量。Al-Ca复合脱氧是更有效的,已经做了一些关于复合脱氧的实验。然而,实验结果不完全符合热力学计算值,因为钙在熔铁脱氧平衡的热力学数据被认为由于测量困难是不可靠的。基于这个

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204/JOURNAL OF BRIDGE ENGINEERING/AUGUST1999

JOURNAL OF BRIDGE ENGINEERING /AUGUST 1999/205 ends.The stress state in each cylindrical strip was determined from the total potential energy of a nonlinear arch model using the Rayleigh-Ritz method. It was emphasized that the membrane stresses in the com-pression region of the curved models were less than those predicted by linear theory and that there was an accompanying increase in ?ange resultant force.The maximum web bending stress was shown to occur at 0.20h from the compression ?ange for the simple support stiffness condition and 0.24h for the ?xed condition,where h is the height of the analytical panel.It was noted that 0.20h would be the optimum position for longitudinal stiffeners in curved girders,which is the same as for straight girders based on stability requirements.From the ?xed condition cases it was determined that there was no signi?cant change in the membrane stresses (from free to ?xed)but that there was a signi?cant effect on the web bend-ing stresses.Numerical results were generated for the reduc-tion in effective moment required to produce initial yield in the ?anges based on curvature and web slenderness for a panel aspect ratio of 1.0and a web-to-?ange area ratio of 2.0.From the results,a maximum reduction of about 13%was noted for a /R =0.167and about 8%for a /R =0.10(h /t w =150),both of which would correspond to extreme curvature,where a is the length of the analytical panel (modeling the distance be-tween transverse stiffeners)and R is the radius of curvature.To apply the parametric results to developing design criteria for practical curved girders,the de?ections and web bending stresses that would occur for girders with a curvature corre-sponding to the initial imperfection out-of-?atness limit of D /120was used.It was noted that,for a panel with an aspect ratio of 1.0,this would correspond to a curvature of a /R =0.067.The values of moment reduction using this approach were compared with those presented by Basler (Basler and Thurlimann 1961;Vincent 1969).Numerical results based on this limit were generated,and the following web-slenderness requirement was derived: 2 D 36,500a a =1?8.6?34 (1) ? ??? t R R F w ?y where D =unsupported distance between ?anges;and F y =yield stress in psi. An extension of this work was published a year later,when Culver et al.(1973)checked the accuracy of the isolated elas-tically supported cylindrical strips by treating the panel as a unit two-way shell rather than as individual strips.The ?ange/web boundaries were modeled as ?xed,and the boundaries at the transverse stiffeners were modeled as ?xed and simple.Longitudinal stiffeners were modeled with moments of inertias as multiples of the AASHO (Standard 1969)values for straight https://www.sodocs.net/doc/7a8180214.html,ing analytical results obtained for the slenderness required to limit the plate bending stresses in the curved panel to those of a ?at panel with the maximum allowed out-of-?atness (a /R =0.067)and with D /t w =330,the following equa-tion was developed for curved plate girder web slenderness with one longitudinal stiffener: D 46,000a a =1?2.9 ?2.2 (2) ? ? ? t R f R w ?b where the calculated bending stress,f b ,is in psi.It was further concluded that if longitudinal stiffeners are located in both the tension and compression regions,the reduction in D /t w will not be required.For the case of two stiffeners,web bending in both regions is reduced and the web slenderness could be de-signed as a straight girder panel.Eq.(1)is currently used in the ‘‘Load Factor Design’’portion of the Guide Speci?cations ,and (2)is used in the ‘‘Allowable Stress Design’’portion for girders stiffened with one longitudinal stiffener.This work was continued by Mariani et al.(1973),where the optimum trans-verse stiffener rigidity was determined analytically. During almost the same time,Abdel-Sayed (1973)studied the prebuckling and elastic buckling behavior of curved web panels and proposed approximate conservative equations for estimating the critical load under pure normal loading (stress),pure shear,and combined normal and shear loading.The linear theory of shells was used.The panel was simply supported along all four edges with no torsional rigidity of the ?anges provided.The transverse stiffeners were therefore assumed to be rigid in their directions (no strains could be developed along the edges of the panels).The Galerkin method was used to solve the governing differential equations,and minimum eigenvalues of the critical load were calculated and presented for a wide range of loading conditions (bedding,shear,and combined),aspect ratios,and curvatures.For all cases,it was demonstrated that the critical load is higher for curved panels over the comparable ?at panel and increases with an increase in curvature. In 1980,Daniels et al.summarized the Lehigh University ?ve-year experimental research program on the fatigue behav-ior of horizontally curved bridges and concluded that the slen-derness limits suggested by Culver were too severe.Equations for ‘‘Load Factor Design’’and for ‘‘Allowable Stress Design’’were developed (respectively)as D 36,500a =1?4?192(3)? ?t R F w ?y D 23,000a =1?4 ?170 (4) ? ? t R f w ?b The latter equation is currently used in the ‘‘Allowable Stress Design’’portion of the Guide Speci?cations for girders not stiffened longitudinally. Numerous analytical and experimental works on the subject have also been published by Japanese researchers since the end of the CURT project.Mikami and colleagues presented work in Japanese journals (Mikami et al.1980;Mikami and Furunishi 1981)and later in the ASCE Journal of Engineering Mechanics (Mikami and Furunishi 1984)on the nonlinear be-havior of cylindrical web panels under bending and combined bending and shear.They analyzed the cylindrical panels based on Washizu’s (1975)nonlinear theory of shells.The governing nonlinear differential equations were solved numerically by the ?nite-difference method.Simple support boundary condi-tions were assumed along the curved boundaries (top and bot-tom at the ?ange locations)and both simple and ?xed support conditions were used at the straight (vertical)boundaries.The large displacement behavior was demonstrated by Mi-kami and Furunishi for a range of geometric properties.Nu-merical values of the load,de?ection,membrane stress,bend-ing stress,and torsional stress were obtained,but no equations for design use were presented.Signi?cant conclusions include that:(1)the compressive membrane stress in the circumfer-ential direction decreases with an increase in curvature;(2)the panel under combined bending and shear exhibits a lower level of the circumferential membrane stress as compared with the panel under pure bending,and as a result,the bending moment carried by the web panel is reduced;and (3)the plate bending stress under combined bending and shear is larger than that under pure bending.No formulations or recommendations for direct design use were made. Kuranishi and Hiwatashi (1981,1983)used the ?nite-ele-ment method to demonstrate the elastic ?nite displacement be-havior of curved I-girder webs under bending using models with and without ?ange rigidities.Rotation was not allowed (?xed condition)about the vertical axis at the ends of the panel (transverse stiffener locations).Again,the nonlinear distribu-

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